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What is a
Diamond?
Diamonds
are one of the two best known forms of carbon, whose hardness
and high disperation of light make them useful for industrial
applications and jewelry. Diamonds are specifically renowned as
a mineral compund with superlative physical qualities —
they make excellent cutting and abrasives because they can be
scratched only by other diamonds, fullerite in its ultrahard
stage, or aggregated diamond nanorods, which also means they hold a polish extremely well and retain luster, hence their use in sparling jewelry. About 130 million carats (26,000 kg) are mined annually, with a total value of nearly 9 billion in USD.
The name ¡°diamond¡± derives from the Ancient Greek word adamas
(or ¡°invincible¡±). They have been treasured as the highest
quality of gemstones since their use as religious iconography in
India at least 2,500 years ago—and also as usage in
drilling and engraving tools that dates to early human history.
Popularity of diamonds has risen since the 19th century because
of increased supply, improved cutting and polishing techniques,
growth in the world economy, and innovative and successful
advertising campaigns. They are commonly judged by the ¡°four
Cs¡±: carat, clarity, color, and cut.
Although synthetics are produced each year at nearly four times
the amount of natural diamonds, the vast majority of synthetic
diamonds produced are small imperfect diamonds suitable only for
industrial-grade use.
Roughly 49% of diamonds originate from central and southern
Africa, although significant sources of the mineral have been
discovered in Canada, India, Russia, Brazil, and Australia. They
are generally mined from dormant volcanic pipes, which are deep
in the Earth where the high pressure and temperature enables the
formation of the crystals. The mining and distribution of
natural diamonds are subjects of frequent controversy—such
as with concerns over the sale of conflict diamonds by African paramilitary & crime groups.
A diamond itself is a transparent crystal of pure carbon consisting of tetrahedrally bonded carbon atoms. Humans have been able to adapt diamonds for many uses because of the material's exceptional physical characteristics. Most notable among these properties are the extreme hardness of diamond, its high dispersion index, and high thermal conductivity. These properties form the basis for most modern applications of diamond.
Hardness
Diamond is the hardest known naturally occurring material, scoring 10 on the relative Mohs scale of mineral hardness and having an absolute hardness value of between 167 and 231 gigapascals in various tests. Diamond's hardness has been known since antiquity, and is the source of its name. However, aggregated diamond nanorods, an allotrope of carbon first synthesized in 2005, are now believed to be even harder than diamond.
The hardest diamonds in the world are diamonds from the New England area in New South Wales, Australia. These diamonds are generally small, perfect to semiperfect octahedra, and are used to polish other diamonds. Their hardness is considered to be a product of the crystal growth form, which is single stage growth crystal. Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws and defect planes in the crystal lattice all of which affect their hardness (Taylor et al. 1990).
Industrial use of diamonds has historically been associated with their hardness; this property makes diamond the ideal material for cutting and grinding tools. It is one of the most known and most useful of more than 3,000 known minerals. As the hardest known naturally occurring material, diamond can be used to polish, cut, or wear away any material, including other diamonds. Common industrial adaptations of this ability include diamond-tipped drill bits and saws, or use of diamond powder as an abrasive. Other specialized applications also exist or are being developed, including use as semiconductors: some blue diamonds are natural semiconductors, in contrast to most other diamonds, which are excellent electrical insulators. Industrial-grade diamonds are either unsuitable for use as gems or synthetically produced, which lowers their price and makes their use economically feasible. Industrial applications, especially as drill bits and engraving tools, also date to ancient times.
The hardness of diamonds also contributes to its suitability as a gemstone. Because it can only be scratched by other diamonds, it maintains its polish extremely well, keeping its luster over long periods of time. Unlike many other gems, it is well-suited to daily wear because of its resistance to scratching—perhaps contributing to its popularity as the
preferred gem in an engagement ring or wedding ring, which are
often worn every day.
Toughness
Unlike hardness, which
only denotes resistance to scratching, diamond's toughness is
only fair to good. Toughness relates to a material's ability to
resist breakage from forceful impact. As with any material, the
macroscopic geometry of a diamond contributes to its resistance
to breakage. Diamond is therefore more fragile in some
orientations than others.
Color
Diamonds occur in a variety of translucent hues —
colorless, steel, blue, yellow, orange, red, green, pink,
brown—or black. Diamonds with a detectable hue to them are
known as colored diamonds. If the color is strong enough, a
stone may be referred to as a fancy colored diamond by the
trade. Colored diamonds contain impurities or structural defects
that cause the coloration, while pure or nearly pure diamonds
are transparent and colorless. Most diamond impurities replace a
carbon atom in the crystal lattice. The most common impurity,
nitrogen, causes a slight to strong yellow coloration depending
upon the type and concentration of nitrogen present. The best
color on a scale of diamond color is D, while the least
desirable is Z, which is yellow.
Thermodynamic
Stability
At surface air pressure (one atmosphere), diamonds are not as
stable as graphite, and so the decay of diamond is
thermodynamically favorable (¥ÄG = −2.99 kJ / mol).
Diamonds will burn at approximately 800 degrees Celsius,
providing that enough oxygen is available. This was shown in the
late 18th century, and previously described during Roman times.
However, owing to a very large kinetic energy barrier, diamonds
are metastable; under normal conditions, it would take an
extremely long time (possibly more than the age of the Universe)
for diamond to decay into graphite.
Electromagnetic
properties
Optical
Properties
Diamonds exhibit a high dispersion of visible light. This strong
ability to split white light into its component colors is an
important phpect of diamond's attraction as a gemstone, giving
it impressive prismatic action that results in so-called fire
in a well-cut stone. The luster of a diamond, a characterization
of how light interacts with the surface of a crystal, is
brilliant and is described as adamantine, which simply
means diamond-like. This is owed to their high refractive index
of 2.417 (at 589.3 nm), which causes total internal reflection
to occur. Some diamonds exhibit fluorescence of various colors
(predominately blue) under long wave ultraviolet light. Nearly
all diamonds fluoresce bluish-white, yellow or green under
X-rays and this property is used extensively in mining to
separate the fluorescing diamond from the non-fluorescing rock.
Most diamonds show no fluorescence although colored diamonds
show a wider range of fluorescence than the blue fluorescence
normally observed in clear diamonds.
Electrical
Properties
Except for most blue diamonds, which are semiconductors,
diamonds are good electrical insulators. Blue diamonds owe their
semiconductive property to boron impurities, which act as a
doping agent and cause p-type semiconductor behavior. Blue
diamonds which are not boron-doped, such as those recently
recovered from the Argyle diamond mine in Australia that owe
their color to an overabundance of hydrogen atoms, are not
semiconductors.
Thermal
Properties
Unlike most electrical insulators, diamond is a good conductor
of heat because of the strong covalent bonding within the
crystal. Most natural blue diamonds contain boron atoms which
replace carbon atoms in the crystal matrix, and also have high
thermal conductivity. Specially purified synthetic diamond has
the highest thermal conductivity (2000–2500 W/(m¡¤K), five
times more than copper) of any known solid at room temperature.
Because diamond has such high thermal conductance it is already
used in semiconductor manufacture to prevent silicon and other
semiconducting materials from overheating.
Natural
history
Formation
Diamonds are formed by prolonged exposure of carbon bearing materials to high pressure and temperature. On Earth, the formation of diamonds is possible because there are regions deep within the Earth that are at a high enough pressure and temperature that the formation of diamonds is thermodynamically favorable. Under continental crust, diamonds form starting at depths of about 150 kilometers (90 miles), where pressure is roughly 5 gigapascals and the temperature is around 1200 degrees Celsius (2200 degrees Fahrenheit). Diamond formation under oceanic crust takes place at greater depths because of higher temperatures, which require higher pressure for diamond formation. Long periods of exposure to these high pressures and temperatures allow diamond crystals to grow larger.
Through studies of carbon isotope ratios (similar to the methodology used in carbon dating) except using the stable isotopes C-12 and C-13, it has been shown that the carbon found in diamonds comes from both inorganic and organic sources. Some diamonds, known as harzburgitic, are formed from
inorganic carbon originally found deep in the Earth's mantle. In
contrast, eclogitic diamonds contain organic carbon
from organic detritus that has been pushed down from the surface
of the Earth's crust through subduction (see plate tectonics)
before transforming into diamond. These two different source
carbons have measurably different 13C:12C ratios. Diamonds that have come to the Earth's surface are generally very old, ranging from under 1 billion to 3.3 billion years old.
Diamonds occur most often as euhedral or rounded octahedra and twinned octahedra known as macles or maccles.
As diamond's crystal structure has a cubic arrangement of the
atoms, they have many facets that belong to a cube, octahedron,
rhombicosidodecahedron, tetrakis hexahedron or disdyakis
dodecahedron. The crystals can have rounded off and unexpressive
edges and can be elongated. Sometimes they are found grown
together or form double "twinned" crystals grown
together at the surfaces of the octahedron. This is all due to
the conditions in which they form. Diamonds (especially those
from secondary deposits) are commonly found coated in nyf, an opaque gum-like skin.
Diamonds can also form in other natural high-pressure, high-temperature events. Very small diamonds, known as microdiamonds
or nanodiamonds, have been found in impact craters
where meteors strike the Earth and create shock zones of high
pressure and temperature where diamond formation can occur.
Microdiamonds are now used as one indicator of ancient meteorite
impact sites.
Surfacing
Diamond-bearing rock is forced close to the surface through deep-origin volcanic eruptions. The magma for such a volcano must originate at a depth where diamonds can be formed, 90 miles (150 km) deep or more (three times or more the depth of source magma for most volcanoes); this is a relatively rare occurrence. Below these typically small surface volcanic craters are formations known as volcanic pipes, which contain material that was pushed toward the surface of the earth by volcanic action, but did not erupt before the volcanic activity ceased. Diamond-bearing volcanic pipes are most commonly found in the oldest regions of continental crust, which relates to the fact that these areas are the coolest portions of the earth's crust, and therefore diamonds can form at the shallowest depths.
The magma in such volcanic pipes is usually one of two characteristic types, which cool into igneous rock known as either kimberlite or lamproite. The magma itself does not contain diamond; instead, it acts as an elevator that carries deep-formed rocks and material upward. These rocks are characteristically rich in magnesium bearing olivine, pyroxene, and amphibole minerals which are usually altered to serpentine under near surface conditions. Certain indicator minerals
typically occur within diamondiferous kimberlites and are used
as mineralogic tracers in the search for diamond deposits by
prospectors. These minerals are rich in chromium (Cr) or
titanium (Ti), elements which impart bright colors to the
minerals. The most common indicator minerals are chromian
garnets (usually bright red Cr-pyrope, and occasionally green
ugrandite-series garnets), eclogitic garnets, orange Ti-pyrope,
red high chromian spinels, dark chromite, bright green Cr-diopside,
glassy green olivine, black picroilmenite, and magnetite.
Kimberlite deposits are known as blue ground for the
deeper serpentinized part of the deposits, or as yellow
ground for the near surface smectite clay and carbonate weathered and oxidized portion.
Once diamonds have been forced to the surface by magma in a volcanic pipe, they may erode out and be distributed over a large area. A volcanic pipe containing diamonds is known as a primary
source of diamonds. Secondary sources of diamonds include all areas where a significant number of diamonds, eroded out of their kimberlite or lamproite matrix, accumulate because of water or weather action. These include alluvial deposits and deposits along existing and ancient shorelines, where loose diamonds tend to accumulate because of their approximate size and density. Diamonds have also rarely been found in deposits left behind by glaciers (notably in Wisconsin and Indiana); however, in contrast to alluvial deposits, glacial deposits are not known to be of significant concentration and are therefore not viable commercial sources of diamond.
Diamonds can also be brought to the surface through certain processes which may occur when two continental plates collide forcefully, although this phenomenon is less understood and currently assumed to be uncommon.
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